Search
Now showing items 1-3 of 3
Synthesis and characterization of pn monoanionic ligands and their reactivity with actinides
(University of Missouri--Columbia, 2021)
understand the reactivity of actinides and how it differs from other radio toxins. In collaboration with Stephan Hohloch at the University of Innsbruck our group developed a new preliminary organoactinide complex, NP-Th containing the ligand (N-(2...
Synthesis, characterization, and reactivity of actinide complexes bearing An-E bonds (An = Th, U; E = P, As)
(University of Missouri--Columbia, 2021)
-metal phosphinidiide complexes of the form {(C5Me5)2Th[[mu]2-P(Mes)][[mu]2-P(H)Mes]M(L)n}2 (L = THF, Et2O), where computational (DFT) analysis and 31P NMR spectroscopy suggests significant Th-P multiple bond character. Reaction of (C5Me5)2Th[P(H)Mes]2 with CuMes in a 2...
Synthesis and reactivity of low-valent uranium and neptunium complexes
(University of Missouri--Columbia, 2019)
Chapter 1 reports the synthesis and characterization of U(IV) and Np(IV) selenium bis(phenolate) complexes. The reaction of the U(IV) complex with half an equivalent of p-benzoquinone results in the formation of a U(V)--U(V) ...